
3370964.05 04/2014 GB/D/F/E
10
WIKA operating instructions models TR10-L, TC10-L (Ex d)
GB
3.2 Thermocouples
3.2.1 Sensor types
Type
Recommended max. operating temperature
K 1,200 °C
J 800 °C
E 800 °C
N 1,200 °C
3.2.2 Potential measurement uncertainties
Important factors which counteract the long-term stability of thermocouples.
Ageing eects/poisoning
■
Oxidation processes in thermocouples which are not appropriately protected (“bare”
thermocouple wires) result in falsications of the characteristic curves.
■
Foreign atoms (poisoning) that diuse into the original alloys lead to changes of these
original alloys and thus falsify the characteristic curve.
■
The inuence of hydrogen leads to the embrittlement of the thermocouples.
The Ni leg of the type K thermocouple is often damaged by sulphur which is contained in
exhaust gases, for example. Type J and T thermocouples age slightly, as the pure metal leg
oxidises rst.
In general, rising temperatures cause accelerated ageing eects.
Green rot
If type K thermocouples are used at temperatures from approx. 800 °C to 1,050 °C,
considerable changes of the thermoelectric voltage can occur. The cause of this is a
chromium depletion or the chrome oxidation in the NiCr leg (+ leg). The precondition
for this is a low concentration of oxygen or steam in the immediate environment of the
thermocouple. The nickel leg is not aected by it. The consequence of this eect is a drift of
the measured value caused by decreasing thermoelectric voltage. This eect is accelerated
if there is a shortage of oxygen (reducing atmosphere), since a complete oxide layer, which
would protect it from further oxidation of the chromium, cannot be formed on the surface of
the thermocouple.
The thermocouple is permanently destroyed by this process. The name green rot is derived
from the greenish shimmering colouration on the breaking point of the wire.
The thermocouple type N has in this regard an advantage due to its silicium content. Here, a
protective oxide layer forms on its surface under the same conditions.
3. Specications
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